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two.2]decane core and defining the geometry in the exocyclic double bond. The activation energies of formation in the vinyl-gold intermediates ended up calculated and uncovered a silyl enol ether with an unprotected indole moiety as an appropriate precursor for your Toste cyclization. This six-m

two.2]decane core and defining the geometry on the exocyclic double bond. The activation energies of development on the vinyl-gold intermediates were calculated and uncovered a silyl enol ether by having an unprotected indole moiety as a suitable precursor for the Toste cyclization. This 6-move